Applied Chemistry for Advanced Metal Protection and Sustainable Energy Systems 1BCHEM102-202
Course Code: 1BCHEM102-202
Credits: 04
CIE Marks: 50
SEE Marks: 50
Total Marks: 100
Exam Hours: 03
Total Hours of Pedagogy: 40H + 12L
Teaching Hours/Weeks: [L:T:P:S] 3:0:2:0
Corrosion: Introduction, electrochemical theory of corrosion, types of corrosion-differential
metal and differential aeration corrosion-waterline and pitting corrosion, corrosion controlmetal coating; galvanization, surface conversion coating; anodization and cathodic protection;
sacrificial anode method, corrosion penetration rate (CPR) – Introduction and numerical
problems.
Coating Technologies: Introduction, technological importance, electroplating – electroplating of
chromium-decorative and hard chromium, electro-less plating – electroless plating of Nickel,
difference between electroplating and electroless plating.
Fuels: Introduction, calorific value, determination of calorific value using bomb’s calorimeter,
numerical problems on GCV and NCV. Knocking in internal combustion (IC) engines – knocking
mechanism in IC engines. Anti-knocking agents – methyl tertiary butyl ether (MTBE) and ethyl
tert-butyl ether (ETBE). Importance of octane and cetane rating of fuel.
Green Fuels: Introduction, power alcohol – properties, applications and its limitations, biodiesel
– synthesis by trans-esterification method, advantages and its applications. Production of green
hydrogen by photocatalytic water splitting and its advantages, hydrogen storage – introduction,
advantages and limitations of metal hydride and ammonia as chemical hydrogen carriers.
Nanomaterials: Introduction, synthesis of TiO2 nanoparticles by sol-gel method and its uses in
catalytic converter. Size-dependent properties of nanomaterial-surface area, catalytical, electrical
and thermal conductivity. Graphene – Synthesis by chemical vapor deposition (CVD) method,
properties and engineering applications. Role of carbon nanotubes (CNTs) in energy devices.
Energy Systems: Batteries – Introduction, classification of batteries, characteristics-capacity,
power density, shelf life and cycle life. Construction, working and applications of Li-ion battery.
Fuel cells: Introduction, construction and working of solid oxide fuel cells (SOFCs) and its uses
in auxiliary power units (APUs). Differences between fuel cell and battery. Solar photovoltaic
cells (PV cells) – construction, working, advantages and limitations.
Engineering Polymers: Introduction, molecular weight of polymers – number average and
weight average molecular weight, numerical problems. Synthesis, properties and engineering
applications of chlorinated polyvinyl chloride (CPVC), polymethyl methacrylate (PMMA).
Structure-properties relationship of polymers (Crystallinity, Strength, Elasticity and chemical
resistivity]. Glass transition temperature (Tg), factor affecting Tg and its significance.
Polymer Composites: Introduction, fiber-reinforced polymers (FRPs); Kevlar – Synthesis,
properties and industrial applications. Carbon-fiber – Preparation from Polyacrylonitrile (PAN),
properties and industrial applications.
3D Printing materials: Introduction, synthesis, properties and applications of polylactic acid
(PLA) resin.
Lubricants: Introduction, classification, ideal properties and applications. Lubricant testing;
experimental determination of viscosity using Ostwald’s viscometer.
Industrial Coolants: Introduction, types – water and oil-based coolants, properties and
industrial applications.
Industrial effluents: Introduction, determination of COD and numerical problems.
Sensors: Introduction, potentiometric sensor – principle and its application in the estimation of
iron in steel industry effluent. Conductometric sensor – principle and its application in the
estimation of acid mixture in electrochemical bath effluent. pH sensor – principle and its
application in the estimation of pKa of acid electrolyte.
